Development and Characterization of Non-ConventionalMicro-Porous Layers for PEM Fuel Cells

Energies

Paola Gallo Stampino¹  Saverio Latorrata¹  Cinzia Cristiani¹  Giovanni Dotelli¹  Riccardo Balzarotti¹ 

[1] Politecnico di Milano, Dipartimento di Chimica, Materiali e Ingegneria Chimica "G. Natta",Piazza Leonardo da Vinci 32, 20133 Milano, Italy;

关键词: PEMFCs;    perfluoropolyethers;    electrochemical impedance spectroscopy;    micro-porous layer;    hydrophobic coatings;   

DOI  :  10.3390/en8077070

来源: DOAJ

【 摘 要 】

Gas diffusion medium (GDM) is a crucial component in proton exchange membrane fuel cells (PEMFCs). Being composed of a gas diffusion layer (GDL) with a micro-porous layer (MPL) coated onto it, it ensures a proper water management due to the highly hydrophobic materials employed in cell assembly. In current commercial applications, the desired water repellent behaviour is usually obtained by using polytetrafluoroethylene (PTFE). In this work, Fluorolink® P56 (Solvay Specialty Polymers, Milan, Italy),a commercially available, anionic, segmented high molecular weight polyfluorourethane with perfluoropolyether groups was extensively evaluated as an alternative to PTFE formicro-porous layer hydrophobization. A change in polymer used is desirable in order to simplify the production process, both in terms of ink formulation and thermal treatment,as well as to get a higher hydrophobicity and, consequently, more efficient water management. Innovative prepared samples were compared to a PTFE-based GDM, in order to assess differences both from morphological and from an electrochemical point of view.

【 授权许可】

Unknown