Water-sensitive multicolor luminescence in lanthanide-organic framework for anti-counterfeiting

Opto-Electronic Advances

Tifeng Xia¹  Wenqian Cao¹  Guodong Qian¹  Yuanjing Cui¹  Yu Yang¹ 

[1] State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China;

关键词: metal-organic framework;    multicolor luminescence;    anti-counterfeiting;   

DOI  :  10.29026/oea.2021.200063

来源: DOAJ

【 摘 要 】

The development of high-level anti-counterfeiting techniques is of great significance in economics and security issues. However, intricate reading methods are required to obtain multi-level information stored in different colors, which greatly limits the application of anti-counterfeiting technology on solving real world problems. Herein, we realize multicolor information anti-counterfeiting under simply external stimulation by utilizing the functional groups and multiple emission centers of lanthanide metal organic framework (Ln-MOFs) to tune luminescence color. Water responsive multicolor luminescence represented by both the tunable color from red to blue within the visible region and high sensitive responsivity has been achieved, owing to the increased nonradiative decay pathways and enhanced Eu3+-to-ligand energy back transfer. Remarkably, information hidden in different colors needs to be read with a specific water content, which can be used as an encryption key to ensure the security of the information for high-level anti-counterfeiting.

【 授权许可】

Unknown