Crystal structure of 2-[(E)-2-(2-chlorobenzylidene)hydrazin-1-yl]-4-phenyl-1,3-thiazole

Acta Crystallographica Section E

Alaa A. Hassan¹  Shaaban K. Mohamed²  Joel T. Mague³  Mehmet Akkurt⁴  Mustafa R. Albayati⁵ 

[1] Chemistry Department, Faculty of Science, Mini University, 61519 El-Minia, Egypt;Chemistry and Environmental Division, Manchester Metropolitan University, Manchester M1 5GD, England;Department of Chemistry, Tulane University, New Orleans, LA 70118, USA;Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey;Kirkuk University, College of Science, Department of Chemistry, Kirkuk, Iraq;

关键词: crystal structure;    1,3-thiazole;    hydrogen bonding;    hydrogen-bonded dimers;   

DOI  :  10.1107/S1600536814016298

来源: DOAJ

【 摘 要 】

The asymmetric unit of the title compound, C16H12ClN3S, contains two independent molecules whose conformations differ primarily in the orientations of the phenyl and chlorobenzene rings with respect to the thiazole ring. In the first molecule, the dihedral angles are 3.0 (1) and 9.2 (1)°, respectively, for the phenyl ring and the chlorobenzene ring, while in the second molecule, the corresponding angles are 18.6 (1) and 23.4 (1)°. In the crystal, the two independent molecules are associated via complementary N—H...N hydrogen bonds into a dimer. These dimers are associated through weak C—H...Cl and C—H...S interactions into supramolecular chains propagating along the a-axis direction.

【 授权许可】

Unknown