Preparation of Cellulose Films from Sustainable CO2/DBU/DMSO System

Polymers

Zaiquan Li¹  Haibo Xie¹  Jianyun Gan¹  Gang Hu²  Lihua Zhang²  Longming Jin³  Long Cai³  Qiang Zheng³ 

[1] Engineering, College of Materials &Metallurgy, Guizhou University, West Campus, Huaxi District, Guiyang 550025, China;;Department of Polymer Materials &

关键词: CO₂;    cellulose dissolution;    cellulose films;    regeneration;   

DOI  :  10.3390/polym11060994

来源: DOAJ

【 摘 要 】

Cellulose films are regarded as sustainable materials having wide applications in food packaging, separation, etc. Their preparation substantially relies on sufficient dissolution. Herein, various celluloses adequately dissolved in a new solvent system of carbon dioxide,1, 8-diazabicyclo [5.4.0] undec-7-ene and dimethyl sulfoxide (CO₂/DBU/DMSO) were made in to films using different regeneration reagents. The films regenerated from ethanol and methanol presented homogeneous and smooth surfaces, while those from 5 wt % NaOH (aq.) and 5 wt % H₂SO₄ (aq.) showed rough surfaces, as analyzed using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The films regenerated from 5 wt % NaOH (aq.) and 5 wt % H₂SO₄ (aq.) rendered cellulose II structures, while those regenerated from alcohols had amorphous structures as evidenced using fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) results. The films made of microcrystalline cellulose had a good light transmittance of about 90% at 800 nm with a tensile strength of 55 MPa and an elongation break of 6.5%, while those from wood pulp cellulose demonstrated satisfactory flexibility with a tensile strength of 91 MPa and an elongation break of 9.0%. This research reports a simple, environmental, and sustainable method to prepare cellulose films of good mechanical properties.

【 授权许可】

Unknown