Doping of Chlorine from a Neoprene Adhesive Enhances Degradation Efficiency of Dyes by Structured TiO2-Coated Photocatalytic Fabrics

Catalysts

Bing Zhang¹  Ding Cao²  Xu Xiang²  Pin Ren²  Yanjun Lin²  Zhen Cao²  Tingting Zhang²  Liren Wang² 

[1] School of Chemical Engineering, Zhengzhou University, 100 Science Avenue, Zhengzhou 450001, China;State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;

关键词: tio₂-coated fabrics;    self-sensitizing degradation;    neoprene;    chlorine doping;    oxygen vacancies;   

DOI  :  10.3390/catal10010069

来源: DOAJ

【 摘 要 】

We demonstrate that using neoprene as a binder during the fabrication of TiO₂-coated fabrics enhances the rates of photodegradation of dyes by the fabrics. The neoprene binder simultaneously modifies the surface of the TiO₂ particles with Cl and dopes the TiO₂ with Cl, without requiring high temperatures or other harsh laboratory treatments. The adsorption of chlorine on the surface and doping of the lattice with chlorine were confirmed by X-ray photoelectron spectroscopy. The chloride ions adsorbed onto the TiO₂ surface introduces a negative surface charge that enhances electrostatic adsorption of cationic dyes, and greatly improves the self-sensitizing degradation performance of the dyes. Chloride ions replace lattice oxygen atoms in TiO₂, inducing lattice oxygen vacancies, that reduce the apparent band gap of the TiO₂ particles, enhancing its absorption of visible light, and further increasing the photocatalytic activity of the composite-coated fabric. The degradation rates of RhB and MB over 50 min were 95.2% and 96.0%, respectively. The degradation rate for MO reached 95.4% after 180 min. We also show that •OH and •O²⁻ are active agents in the dye-degradation mechanism. Moreover, the photocatalytic performance of the composite-coated fabric was unchanged after eight cycles of photocatalytic degradation of RhB, demonstrating that the photocatalyst-coated fabrics was highly recyclable.

【 授权许可】

Unknown