Nonanebis(peroxoic acid): a stable peracid for oxidative bromination of aminoanthracene-9,10-dione

Beilstein Journal of Organic Chemistry

Vilas Venunath Patil¹  Ganapati Subray Shankarling¹ 

[1] Department of Dyestuff Technology, Institute of Chemical Technology, N. P. Marg, Matunga, Mumbai - 400019, India. Tel.: [phone], Fax: [phone];

关键词: aminoanthracene-9,10-dione;    benzanthrone;    KBr;    nonanebis(peroxoic acid);    oxidative bromination;   

DOI  :  10.3762/bjoc.10.90

来源: DOAJ

【 摘 要 】

A new protocol for the oxidative bromination of aminoanthracene-9,10-dione, which is highly deactivated towards the electrophilic substitution is investigated. The peracid, nonanebis(peroxoic acid), possesses advantages such as better stability at room temperature, it is easy to prepare and non-shock sensitiv as compared to the conventional peracids. The present protocol has a broad scope for the bromination of various substituted and unsubstituted aminoanthracene-9,10-diones.

【 授权许可】

Unknown