Catalysts | |
Terpolymerization of CO2 with Epoxides and Cyclic Organic Anhydrides or Cyclic Esters | |
David Hermann Lamparelli1  Carmine Capacchione1  | |
[1] Dipartimento di Chimica e Biologia “A. Zambelli”, Università degli Studi di Salerno, Via Giovanni Paolo II n°132, 84184 Fisciano, Italy; | |
关键词: CO2; epoxides; cyclic esters; cyclic anhydrides; ROCOP; ROP; | |
DOI : 10.3390/catal11080961 | |
来源: DOAJ |
【 摘 要 】
The synthesis of polymeric materials starting from CO2 as a feedstock is an active task of research. In particular, the copolymerization of CO2 with epoxides via ring-opening copolymerization (ROCOP) offers a simple, efficient route to synthesize aliphatic polycarbonates (APC). In many cases, APC display poor physical and chemical properties, limiting their range of application. The terpolymerization of CO2 with epoxides and organic anhydrides or cyclic esters offers the possibility, combining the ROCOP with ring-opening polymerization (ROP), to access a wide range of materials containing polycarbonate and polyester segments along the polymer chain, showing enhanced properties with respect to the simple APC. This review will cover the last advancements in the field, evidencing the crucial role of the catalytic system in determining the microstructural features of the final polymer.
【 授权许可】
Unknown