Chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) dichloride monohydrate

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C. Maharaja Mahalakshmi¹  K. Anbalagan²  A. SubbiahPandi³  Y. AaminaNaaz³ 

[1] Department of Chemistry, Chellammal Womens College, Chennai 600 032, India;Department of Chemistry, Pondicherry University, Pondicherry 605 014, India;Department of Physics, Presidency College (Autonomous), Chennai 600 005, India;

关键词: crystal structure;    ethane-1,2-diamine;    fluoroaniline ligand;    cobalt(III) complex;    hydrogen bonding;    C—H...Cl interactions;   

DOI  :  10.1107/S2414314619003274

来源: DOAJ

【 摘 要 】

The hydrated title salt, [CoCl(C6H6FN)(C2H8N2)2]Cl2·H2O, comprises of one chloridobis(ethane-1,2-diamine)(4-fluoroaniline)cobalt(III) cation, two chloride counter-anions and a water molecule of crystallization. The CoIII ion has a distorted octahedral environment and is surrounded by four N atoms in the equatorial plane, with a fifth N atom and one Cl− ligand occupying the axial positions. One of the methylene C groups in one of the ethane-1,2-diamine ligands is disordered over two set of sites in a 0.832 (10):0.168 (10) ratio. In the crystal, the complex cation, the two counter-anions and the water molecule of crystallization are linked via N—H...Cl, O—H...Cl and C—H...Cl hydrogen bonds, generating rings with R42(8), R21(6), R42(10) and R22(6) graph-set motifs within a three-dimensional network.

【 授权许可】

Unknown