Structural and Thermal Properties of Ethylene-Norbornene Copolymers Obtained Using Vanadium Homogeneous and SIL Catalysts

Polymers

Anna Bihun-Kisiel¹  Paweł Groch¹  Aleksandra Piontek¹  Wioletta Ochędzan-Siodłak¹ 

[1] Faculty of Chemistry, Opole University, Oleska 48, 45-052 Opole, Poland;

关键词: ethylene;    norbornene;    copolymerization;    post-metallocene catalyst;    NMR investigation;    DSC and SSA investigation;   

DOI  :  10.3390/polym12112433

来源: DOAJ

【 摘 要 】

The series of ethylene-norbornene (E-NB) copolymers was obtained using different vanadium homogeneous and supported ionic liquid (SIL) catalyst systems. The ¹³C and ¹H NMR (carbon and proton nuclear magnetic resonance spectroscopy) together with differential scanning calorimetry (DSC) were applied to determine the composition of copolymers such as comonomer incorporation (C_NB), monomer dispersity (MD), monomer reactivity ratio (r_e), sequence length of ethylene (l_e) and tetrad microblock distributions. The relation between the type of catalyst, reaction conditions and on the other hand, the copolymer microstructure, chain termination reaction analyzed by the type of unsaturation are discussed. In addition, the thermal properties of E-NB copolymers such as the melting and crystallization behavior, like also the heterogeneity of composition described by successive the self-nucleation and annealing (SSA) and the dispersity index (DI) were determined.

【 授权许可】

Unknown