Rhodium-catalyzed borylative carbon monoxide reduction to gem-diborylmethane

Catalysis Communications

Jian-Xing Xu¹  Xiao-Feng Wu¹  Fu-Peng Wu² 

[1] Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Science, 116023 Dalian, Liaoning, China;Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany;

关键词: Rhodium catalyst;    Carbon monoxide;    Gem-Diborylmethane;    Reduction;    Borylation;   

DOI  :  

来源: DOAJ

【 摘 要 】

Herein, we developed a rhodium-catalyzed reduction of CO with bis(pinacolato)diboron (B2pin2) under atmospheric pressure of CO with silane as the hydride source, gem-diborylmethane [H2C(Bpin)2] as a versatile and fundamental C1 compound can be formed. Notably, this is the first example on transition metal-catalyzed borylation of CO.

【 授权许可】

Unknown