Nitrogen-Doped Carbon for Red Phosphorous Based Anode Materials for Lithium Ion Batteries

Materials

Yumin Qian¹  Xiangming He²  Li Wang³  Jiaoyang Li⁴ 

[1]New Energy Technology, Tsinghua University, Beijing 100084, China

[2]Soft Materials, Soochow University, Suzhou 215123, China

[3]

[4]Institute of Functional Nano &

[5]Institute of Nuclear &

关键词: nitrogen-doped carbon;    red phosphorous;    anode materials;    lithium ion batteries;   

DOI  :  10.3390/ma11010134

来源: DOAJ

【 摘 要 】

Serving as conductive matrix and stress buffer, the carbon matrix plays a pivotal role in enabling red phosphorus to be a promising anode material for high capacity lithium ion batteries and sodium ion batteries. In this paper, nitrogen-doping is proved to effective enhance the interface interaction between carbon and red phosphorus. In detail, the adsorption energy between phosphorus atoms and oxygen-containing functional groups on the carbon is significantly reduced by nitrogen doping, as verified by X-ray photoelectron spectroscopy. The adsorption mechanisms are further revealed on the basis of DFT (the first density functional theory) calculations. The RPNC (red phosphorus/nitrogen-doped carbon composite) material shows higher cycling stability and higher capacity than that of RPC (red phosphorus/carbon composite) anode. After 100 cycles, the RPNC still keeps discharge capacity of 1453 mAh g−1 at the current density of 300 mA g−1 (the discharge capacity of RPC after 100 cycles is 1348 mAh g−1). Even at 1200 mA g−1, the RPNC composite still delivers a capacity of 1178 mAh g−1. This work provides insight information about the interface interactions between composite materials, as well as new technology develops high performance phosphorus based anode materials.

【 授权许可】

Unknown