Crystal structure of poly[(2,2′-bipyridine-κ2N,N′)tetra-μ2-cyanido-κ4C:N;κ4N:C-manganese(II)disilver(I)]

Acta Crystallographica Section E: Crystallographic Communications

卷:71

Chatphorn Theppitak¹  Kittipong Chainok² 

[1] Department of Chemistry, Faculty of Science, Naresuan University, Muang, Phitsanulok, 65000, Thailand;

[2] Department of Physics, Faculty of Science and Technology, Thammasat University, Khlong Luang, Pathum Thani, 12120, Thailand;

关键词: crystal structure;    dicyanoargentate(I);    manganese(II);    triple interpenetration;   

DOI  :  10.1107/S205698901501676X

来源: DOAJ

【 摘 要 】

The title compound, [Ag2Mn(CN)4(C10H8N2)]n or Mn(bipy){Ag(CN)2}2 (bipy = 2,2′-bipyridine) is isostructural with Cd(bipy){Au(CN)2}2 [Guo et al. (2009). CrystEngComm, 11, 61–66]. The MnII atom has crystallographically imposed twofold symmetry and a distorted octahedral coordination sphere consisting of six N atoms from one bipyridine ligand and four dicyanoargentate(I) anions, [Ag(CN)2]−, while the AgI atom of the complex anion displays the expected linear geometry. Each [Ag(CN)2]− unit connects to two neighbouring [Mn(bipy)]2+ cations to give an threefold interpenetrating quartz-like three-dimensional framework. No directional interactions beyond van der Waals contacts are observed.

【 授权许可】

Unknown