(Thiocyanato-κS)tris(triphenylphosphane-κP)silver(I)

IUCrData

卷:2

Arunpatcha Nimthong-Roldán¹  Monpariya Romyen²  Yupa Wattanakanjana²  Paramee Sripa² 

[1] Department of Chemistry, Boston University, Massachusetts 02215, USA;

[2] Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;

关键词: crystal structure;    hydrogen bonding;    silver(I);    thiocyanate;   

DOI  :  10.1107/S2414314617011853

来源: DOAJ

【 摘 要 】

In the mononuclear title complex, [Ag(SCN)(C18H15P)3], the AgI center is in a slightly distorted tetrahedral coordination geometry formed by one S atom from a terminal thiocyanate ligand and three P atoms from three triphenylphosphane ligands. In the crystal, weak C—H...N hydrogen bonds connect molecules into a two-dimensional network parallel to (10\overline{1}). One of the phenyl rings is disordered over two positions which were refined with an occupancy ratio of 0.715 (16):0.285 (16).

【 授权许可】

Unknown