(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol

International Journal of Molecular Sciences

卷:17

Gaetano A. Tomaselli¹  Andrea Pappalardo¹  Rosa Maria Toscano¹  Giuseppe Trusso Sfrazzetto¹  Francesco Paolo Ballistreri¹  Chiara M. A. Gangemi¹ 

[1] Department of Chemical Sciences, University of Catania, Viale Andrea Doria 6, 95125 Catania, Italy;

关键词: epoxidation;    enantioselectivity;    jacobsen catalyst;    hydrogen peroxide;    water;   

DOI  :  10.3390/ijms17071112

来源: DOAJ

【 摘 要 】

Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H2O employing H2O2 as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).

【 授权许可】

Unknown