Iridium and Ruthenium Modified Polyaniline Polymer Leads to Nanostructured Electrocatalysts with High Performance Regarding Water Splitting

Polymers

卷:13

Marie-Agnès Lacour¹  Julien Cambedouzou²  Sophie Tingry²  David Cornu²  Yaovi Holade²  Razik Djara³  Abdelhafid Merzouki³ 

[1] ChemLab, CEDEX 5, 34296 Montpellier, France;

[2] Institut Européen des Membranes, IEM UMR 5635, University of Montpellier, ENSCM, CNRS, 34090 Montpellier, France;

[3] Laboratoire de Physico-Chimie des Hauts Polymères (LPCHP), Université Ferhat Abbas, Sétif 19000, Algeria;

关键词: conducting polymer;    polyaniline;    electrocatalysis;    hydrogen evolution reaction;    oxygen evolution reaction;    water splitting;   

DOI  :  10.3390/polym13020190

来源: DOAJ

【 摘 要 】

The breakthrough in water electrolysis technology for the sustainable production of H₂, considered as a future fuel, is currently hampered by the development of tough electrocatalytic materials. We report a new strategy of fabricating conducting polymer-derived nanostructured materials to accelerate the electrocatalytic hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and water splitting. Extended physical (XRD, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX)) and electrochemical (cyclic voltammetry (CV), linear sweep voltammetry (LSV), electrochemical impedance spectroscopy (EIS)) methods were merged to precisely characterize the as-synthesized iridium and ruthenium modified polyaniline (PANI) materials and interrogate their efficiency. The presence of Ir(+III) cations during polymerization leads to the formation of Ir metal nanoparticles, while Ru(+III) induces the formation of RuO₂ oxide nanoparticles by thermal treatment; they are therefore methods for the on-demand production of oxide or metal nanostructured electrocatalysts. The findings from using 0.5 M H₂SO₄ highlight an ultrafast electrochemical kinetic of the material PANI-Ir for HER (36 − 0 = 36 mV overpotential to reach 10 mA cm⁻² at 21 mV dec⁻¹), and of PANI-Ru for OER (1.47 − 1.23 = 240 mV overpotential to reach 10 mA cm⁻² at 47 mV dec⁻¹), resulting in an efficient water splitting exactly at its thermoneutral cell voltage of 1.45 V, and satisfactory durability (96 h).

【 授权许可】

Unknown