per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane

Molecules

卷:25

Nicholas Pearce¹  E.Stephen Davies¹  NeilR. Champness¹ 

[1] School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK;

关键词: pillararene;    rotaxane;    electrochemistry;    voltammetry;    oxidation;   

DOI  :  10.3390/molecules25071627

来源: DOAJ

【 摘 要 】

1,4-dimethoxypillar[5]arene undergoes reversible multielectron oxidations forming stable radical cations, a property retained when incorporated in [2]rotaxanes, suggesting that pillar[5]arenes can be employed as viable, yet unreported, electron donors.

【 授权许可】

Unknown