Trace-Level Determination of Polycyclic Aromatic Hydrocarbons in Dairy Products Available in Spanish Supermarkets by Semi-Automated Solid-Phase Extraction and Gas Chromatography–Mass Spectrometry Detection

Foods

卷:11

Evaristo Ballesteros¹  Laura Palacios Colón¹  Andrés J. Rascón¹ 

[1] Department of Physical and Analytical Chemistry, E.P.S of Linares, University of Jaén, 23700 Linares, Spain;

关键词: dairy product composition;    priority pollutants;    polycyclic aromatic hydrocarbons;    health risk;    liquid–liquid extraction;    continuous solid-phase extraction;   

DOI  :  10.3390/foods11050713

来源: DOAJ

【 摘 要 】

Polycyclic aromatic hydrocarbons (PAHs) have been classified as priority pollutants by the U.S. Environmental Protection Agency (EPA) and the European Commission on the grounds of their carcinogenic, mutagenic and teratogenic properties. Because of their ubiquity in industrial processes and the environment, PAHs can reach milk and dairy products and, eventually, humans. In this work, a new method was developed to detect and quantify sixteen of the EPA’s priority PAHs in commercial milk and dairy products. The method involves liquid–liquid extraction (LLE) followed by semi-automated solid-phase extraction (SPE) to clean up and preconcentrate the analytes prior their detection and quantification by gas chromatography–mass spectrometry (GC–MS). The proposed method provided high precision (relative standard deviation < 11.5%), recoveries of 80–107% and low detection limits (1–200 ng/kg). The method was applied to analyze 30 dairy products, the majority of which contained some PAH at concentrations from 7.1 to 1900 ng/kg. The most-detected analytes were the lighter PAHs (naphthalene, acenaphthylene, fluorene and phenanthrene). None of the samples, however, contained more than four PAHs.

【 授权许可】

Unknown