Sustainable Aromatic Aliphatic Polyesters and Polyurethanes Prepared from Vanillin-Derived Diols via Green Catalysis

Polymers

卷:12

Qin Chen¹  Tianhua Ren¹  Haibo Xie²  IanD. V. Ingram²  Changbo Zhao²  Caijuan Huang³  Xiankui Zeng³ 

[1] Metallurgy, Guizhou University, West Campus, Huaxi District, Guiyang 550025, China;

[2] Department of Polymer Materials &

[3] Engineering, College of Materials &

关键词: lignin;    vanillin;    green catalysis;    full bio-based polyesters;    polyurethane;   

DOI  :  10.3390/polym12030586

来源: DOAJ

【 摘 要 】

The design and preparation of polymers by using biobased chemicals is regarded as an important strategy towards a sustainable polymer chemistry. Herein, two aromatic diols, 4-(hydroxymethyl)-2-methoxyphenol and 2-(4-(hydroxymethyl)-2-methoxyphenoxy)ethanol, have been prepared in good yields through the direct reduction of vanillin and hydroxyethylated vanillin (4-(2-hydroxyethoxy)-3-methoxybenzaldehyde) using NaBH₄, respectively. The diols were submitted to traditional polycondensation and polyaddition with acyl chlorides and diisocyanatos, and serials of new polyesters and polyurethanes were prepared in high yields with moderate molecular weight ranging from 17,000 to 40,000 g mol⁻¹. Their structures were characterized by ¹H NMR, ¹³C NMR and FTIR, and their thermal properties were studied by TGA and differential scanning calorimetry (DSC), indicating that the as-prepared polyesters and polyurethanes have T_g in the range of 16.2 to 81.2 °C and 11.6 to 80.4 °C, respectively.

【 授权许可】

Unknown