Structural Adhesives Tapes Based on a Solid Epoxy Resin and Multifunctional Acrylic Telomers

Polymers

卷:13

Agnieszka Kowalczyk¹  Krzysztof Kowalczyk¹  Mateusz Weisbrodt¹ 

[1] Department of Chemical Organic Technology and Polymer Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, 70-322 Szczecin, Poland;

关键词: epoxy resins;    thermoset polymers;    structural adhesives;    acrylic monomers;    telomerization;    mechanical properties;   

DOI  :  10.3390/polym13203561

来源: DOAJ

【 摘 要 】

Thermally curable pressure-sensitive structural adhesives tapes (SATs) were compounded using a solid epoxy resin and multifunctional acrylic telomer solutions (MATs) prepared by a thermally initiated telomerization process in an epoxy diluent containing two kinds of telogens (CBr₄ or CBrCl₃). Dynamic viscosity, K-value, and volatile mater content in MATs (i.e., MAT-T with CBr₄, MAT-B with CBrCl₃) were investigated in relation to telogen type and content. The influence of MATs on the self-adhesive features and curing behavior of UV-crosslinked tapes as well as on the shear strength of thermally cured aluminum–SAT–aluminum joints was investigated as well. Increasing the telogen dose (from 5 to 15 wt. parts) caused significant improvement in the adhesion (+315% and +184%), tack (+147% and +298%), and cohesion (+414% and +1716%) of SATs based on MAT-T and MAT-B, respectively. Additionally, MATs with high telogen content (especially the MAT-T-type) improved the resistance of cured joints to aviation fuel, humidity, and elevated temperature. The highest overlap shear strength values were registered for SATs based on MATs containing 7.5 wt. parts of CBr₄ (16.7 MPa) or 10 wt. parts of CBrCl₃ (15.3 MPa).

【 授权许可】

Unknown