The Impact of Post-Synthetic Linker Functionalization of MOFs on Methane Storage: the Role of Defects

Frontiers in Energy Research

卷:4

Pablo eSerra Crespo¹  Jorge eGascon²  Bernard eDam²  Hans eGeerlings³  Petra Agota Szilagyi⁴ 

[1] Delft Uiversity of Technology;

[2] Delft University of Technology;

[3] Shell Technology Centre;

[4] University of Greenwich;

关键词: Metal-Organic Frameworks;    defects;    methane storage;    Post-synthetic modification;    dangling linker;   

DOI  :  10.3389/fenrg.2016.00009

来源: DOAJ

【 摘 要 】

Natural gas is increasingly being viewed as one of the most viable alternatives to gasoline. Its vehicular application however will only be widespread if safe and high-capacity methane stores are developed. In this work report an over 33% increase in methane uptake on a post-synthetically modified metal-organic framework. The underlying mechanism for this dramatic increase is due to lattice defects formed upon post-synthetic modification. This method may open new approaches to natural gas storage.

【 授权许可】

Unknown