Floating Carbon-Doped TiO2 Photocatalyst with Metallic Underlayers Investigation for Polluted Water Treatment under Visible-Light Irradiation

Catalysts

卷:11

Marius Urbonavičius¹  Simona Tuckute¹  Sarunas Varnagiris¹  Emilija Demikyte¹  Sandra Sakalauskaitė² 

[1] Center for Hydrogen Energy Technologies, Lithuanian Energy Institute, 3 Breslaujos, 44403 Kaunas, Lithuania;

[2] Department of Biochemistry, Faculty of Natural Sciences, Vytautas Magnus University, 44404 Kaunas, Lithuania;

关键词: carbon doped TiO₂;    photocatalysis;    visible light;    Salmonella typhimurium;    metallic underlayers;    floating photocatalyst;   

DOI  :  10.3390/catal11121454

来源: DOAJ

【 摘 要 】

In the current study, we analysed the influence of metallic underlayers on carbon-doped TiO₂ films for RhB decomposition and Salmonella typhimurium inactivation under visible-light irradiation. All the experiments were divided into two parts. First, layered M/C-doped-TiO₂ film structures (M = Ni, Nb, Cu) were prepared by magnetron sputtering technique on borosilicate glass substrates in the two-step deposition process. The influence of metal underlayer on the formation of the carbon-doped TiO₂ films was characterised by X-ray diffractometer, scanning electron microscope, and atomic force microscope. The comparison between the visible-light assisted photocatalytic activity of M/C-doped TiO₂ structures was performed by the photocatalytic bleaching tests of Rhodamine B dye aqueous solution. The best photocatalytic performance was observed for Ni/C-doped-TiO₂ film combination. During the second part of the study, the Ni/C-doped-TiO₂ film combination was deposited on high-density polyethylene beads which were selected as a floating substrate. The morphology and surface chemical analyses of the floating photocatalyst were performed. The viability and membrane permeability of Salmonella typhimurium were tested in cycling experiments under UV-B and visible-light irradiation. Three consecutive photocatalytic treatments of fresh bacteria suspensions with the same set of floating photocatalyst showed promising results, as after the third 1 h-long treatment bacteria viability was still reduced by 90% and 50% for UV-B and visible-light irradiation, respectively. The membrane permeability and ethidium fluorescence results suggest that Ni underlayer might have direct and indirect effect on the bacteria inactivation process. Additionally, relatively low loss of the photocatalyst efficiency suggests that floating C-doped TiO₂ photocatalyst with the Ni underlayer might be seen as the possible solution for the used photocatalyst recovery issue.

【 授权许可】

Unknown