Role of Coating Processes on the Corrosion Kinetics and Mechanism of Zinc in Artificial Seawater

Materials

卷:14

Han-Seung Lee¹  Raihana Jannat Adnin¹  Jitendra Kumar Singh²  Hyun-Min Yang²  Soumen Mandal³ 

[1] Department of Architectural Engineering, Hanyang University, 55 Hanyangdaehak-ro, Sangrok-gu, Ansan-si 15588, Korea;

[2] Innovative Durable Building and Infrastructure Research Center, Hanyang University, 55 Hanyangdaehak-ro, Sangrok-gu, Ansan-si 15588, Korea;

[3] Intelligent Construction Automation Center, Kyungpook National University, 80, Daehak-ro, Buk-gu, Daegu 41566, Korea;

关键词: zinc;    coating;    corrosion;    thermal spray;    electrochemical impedance spectroscopy;    scanning electron microscope;   

DOI  :  10.3390/ma14237464

来源: DOAJ

【 摘 要 】

Zinc (Zn) coating is being used to protect steel structures from corrosion. There are different processes to deposit the coating onto a steel substrate. Therefore, in the present study, a 100 µm thick Zn coating was deposited by arc and plasma arc thermal spray coating processes, and the corrosion resistance performance was evaluated in artificial seawater. Scanning electron microscopy (SEM) results showed that the arc thermal spray coating exhibited splats and inflight particles, whereas plasma arc spraying showed a uniform and dense morphology. When the exposure periods were extended up to 23 d, the corrosion resistance of the arc as well as the plasma arc thermal spray coating increased considerably. This is attributed to the blocking characteristics of the defects by the stable hydrozincite (Zn₅(OH)₆(CO₃)₂).

【 授权许可】

Unknown