Isotopic Analysis of Sugarcane/Petroleum Polyethylene Blends: A Perspective on the Application of Stable Isotope Method (δ 13 C)

Journal of the Brazilian Chemical Society

article

Santos, Victor H. J. M. dos¹  Rodrigues, Luiz F.¹ 

[1] Instituto do Petróleo e dos Recursos Naturais, Pontifícia Universidade Católica do Rio Grande do Sul

关键词: bio-based polymer;    polymer blends;    IRMS;    stable isotope;    radiocarbon;    14C AMS;   

DOI  :  10.21577/0103-5053.20200153

学科分类：内科医学

来源: SciELO

【 摘 要 】

In the present work, we propose the application of stable isotope analysis (δ 13 C) as an auxiliary tool for the inspection of sugarcane/petroleum polyethylene blends. Our results are supported from the analysis of selected samples by accelerator mass spectrometry ( 14 C-AMS). From the results, it was concluded that the δ 13 C method is suitable to discriminate samples derived from sugarcane, petroleum, or its blends. It was also noted that both regression models (δ 13 C method and the δ 13 C vs 14 C-AMS regression) presents potential to estimate the bio-based content; however, future work should focus on validating these models. From the screening model, developed with δ 13 C data, 33.33% of the samples were highlighted as suspected of being out of specification. Thus, the screening method can identify samples most likely to be out of specification and reduce the demand for inspection of biogenic content following the ASTM D6866 standard ( 14 C-AMS).

【 授权许可】

CC BY