Liquid crystallinity and thermal properties of polyhedral oligomeric silsesquioxane/side-chain azobenzene hybrid copolymer

Nanotechnology Reviews

article

Xiaotao Wang¹  Zhuofan Chen¹  Yiwan Huang¹  Xiaotie Ye²  Jiacheng Wang¹  Yuye Yang¹  Xuefeng Li¹  Zuifang Liu¹ 

[1] Hubei Provincial Key Laboratory of Green Materials for Light Industry, Collaborative Innovation Center of Green Light-weight Materials and Processing, and School of Materials and Chemical Engineering, Hubei University of Technology;Lingyun Technology Group Co. Ltd

关键词: polyhedral oligomeric silsesquioxanes;    liquid crystalline behaviors;    azobenzene;    photo-isomerization;    thermal stability;   

DOI  :  10.1515/ntrev-2020-0068

学科分类：社会科学、人文和艺术（综合）

来源: De Gruyter

【 摘 要 】

Acrylic acid-modified polyhedral oligomeric silsesquioxane (AC-POSS) was synthesized by the reaction between the amine groups in polyhedral oligomeric silsesquioxane (POSS) and acrylic acid, which could dissolve in water and can be easily purified. Free-radical copolymerization was applied to synthesize azobenzene liquid crystalline polymer silsesquioxane (LCP-POSS) with different proportions of AC-POSS and liquid crystalline monomers. The trans -isomers of azobenzene moieties in LCP-POSS were gradually transformed to cis -isomers with increasing ultraviolet irradiation time. The photoisomerization reaction of liquid crystalline polymer (LCP) and LCP-POSS showed the first-order dynamic reaction. Compared with the LCP, the photoisomerization rate constant of LCP-POSS was decreased due to the space steric hindrance of the POSS as a rigid segment. The phase transition temperature of liquid crystalline in LCP-POSS increased with increasing POSS content, and the liquid crystalline texture in LCP-POSS became smaller under the polarized light. With further increasing the POSS content (>50 wt%) in LCP-POSS, the ordered structure of the liquid crystalline phase was gradually affected, resulting in one-way liquid crystal (LC) phase behavior. The synthesized LCP-POSS has LC properties, light-responsive properties, and thermal stability. When the POSS is introduced into the LC material, the phase state of the LC material will become more abundant and the LC phase will become more stable. The significance of this study is to develop and extend its applications as stimuli-responsive materials and devices.

【 授权许可】

CC BY