Ferrocene-derived P,N ligands: synthesis and application in enantioselective catalysis

Green Processing and Synthesis

article

Timothy Noël¹  Johan Van der Eycken² 

[1] Department of Chemical Engineering and Chemistry, Eindhoven University of Technology;Laboratory for Organic and Bioorganic Synthesis, Department of Organic Chemistry, Ghent University

关键词: enantioselective catalysis;    ferrocene;    P;    N ligands;   

DOI  :  10.1515/gps-2013-0036

来源: De Gruyter

【 摘 要 】

Due to their unique steric and electronic properties, air-stability and modular structure, chiral hybrid P,N-ferrocenyl ligands play a prominent role in the field of asymmetric catalysis. This report aims to give a concise introduction to the syntheses of chiral hybrid P,N-ferrocenyl ligands and presents an overview of their application in enantioselective catalysis. This review is of special interest to chemists working on ligand design and asymmetric catalysis, as well as to the broader organic and inorganic community.

【 授权许可】

CC BY