Treatment of fluoride in well-water in Khanhhoa, Vietnam by aluminum hydroxide coated rice husk ash

Green Processing and Synthesis

article

Tran Ngoc Tuyen¹  Nguyen Duc Vu Quyen¹  Tran Minh Ngoc¹  Ho Van Minh Hai¹  Tran Ngoc Quang²  Hoang Trong Sy³  Tran Dai Lam⁴ 

[1] Department of Chemistry, College of Sciences, Hue University;Department of Environmental Science, College of Sciences, Hue University;College of Medicine and Pharmacy, Hue University;Graduate University of Science and Technology, Vietnam Academy of Science and Technology

关键词: adsorption;    aluminum hydroxide coated rice husk ash;    fluoride;   

DOI  :  10.1515/gps-2016-0043

来源: De Gruyter

【 摘 要 】

In this study, aluminum hydroxide coated rice husk ash [RHA/Al(OH) 3 ] was synthesized and used for adsorption of fluoride from aqueous solution. The amorphous material containing 20% (w/w) of Al 2 O 3 was obtained by stirring the mixture of RHA burned at 700°C for 60 min and 0.1 m AlCl 3 solution for 30 min. This material possessed porous ordered structure with uniform particle size in the range of 50–100 nm and Brunauer-Emmett-Teller (BET)-specific surface area of 81 m 2 g −1 . The isotherm data were fitted well to Langmuir model, and the maximum monolayer adsorption capacity was found to be 8.2 mg g −1 at 25°C. The kinetic results revealed that the pseudo-second-order rate model fitted the experiments data better than the pseudo-first-order one and demonstrated the chemical nature of the adsorption of fluoride. Thermodynamic parameters in the temperature range 30–70°C showed that the adsorption was a spontaneous and an endothermic process. RHA/Al(OH) 3 can be used for well treatment of fluoride in contaminated well-water in the Ninhhoa district (Khanhhoa province). With the initial fluoride concentration (10.1 mg l −1 ) and the 2 h of treatment process with the dose of 4.0–7.0 g l −1 , the content of fluoride decreased to 0.5–1.5 mg l −1 , which met the acceptable limit of WHO.

【 授权许可】

CC BY