Metallacycles Capabilities in Host–Guest Chemistry

ChemistryOpen

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关键词: energy decomposition analysis;    host–guest chemistry;    metallacycles;    multipole moment analysis;    noncovalent index analysis;   

DOI  :  10.1002/open.201500125

来源: Wiley

【 摘 要 】

Abstract

The perfect host for anions! The nature of host–guest interactions in metallacycle-based complexes was determined by various methodologies. Additionally, by plotting the atomic multipole moment tensors, a clear representation of the higher-order electrostatic interactions within the studied systems, such as dipole–quadrupole and quadrupole–quadrupole forces, was obtained.

【 授权许可】

CC BY-NC-ND   
© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.