A Highly Energetic N‐Rich Zeolite‐Like Metal‐Organic Framework with Excellent Air Stability and Insensitivity

Advanced Science

Jun-Sheng Qin²  Ji-Chuan Zhang¹  Min Zhang²  Dong-Ying Du²  Jing Li²  Zhong-Min Su²  Yuan-Yuan Wang²  Si-Ping Pang¹  Sheng-Hua Li¹ 

[1] School of Materials Science and Engineering, Beijing Institute of Technology, Beijin, P. R. China;Institute of Functional Material Chemistry, Department of Chemistry, Northeast Normal University, Changchun, P. R. China

关键词: air stability;    energetic material;    insensitivity;    N‐rich MOF;   

DOI  :  10.1002/advs.201500150

来源: Wiley

【 摘 要 】

Abstract

A stable N-rich aromatic ligand is employed to prepare energetic zeolite-like metal-organic frameworks. IFMC-1 shows excellent air stability, and the lowest sensitivity toward impact, friction, and electrostatic discharge and the highest predicted heat of detonation among the reported coordination polymers, and even commercial materials (such as trinitrotoluene (TNT)).

【 授权许可】

CC BY   
© 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.