Preparation and characterisation of single-crystalline structure Sb/Bi 2 Te 3 superlattice nanowires

Micro & nano letters

article

Junli Fu¹  Jinbo Shen²  Honglong Shi¹  Yujie Liang¹  Zhen Qu¹  Wenzhong Wang¹ 

[1] School of Science, Minzu University of China;School of Electronic Engineering, Beijing University of Posts and Telecommunications

关键词: superlattices;    nanowires;    nanofabrication;    electrodeposition;    X-ray diffraction;    transmission electron microscopy;    electron diffraction;    antimony;    bismuth compounds;    thermoelectricity;    crystallisation;    single-crystalline structure;    superlattice nanowires;    thermoelectric materials;    thermoelectric generation;    pulsed electrodeposition;    porous anodic alumina oxide;    X-ray diffraction;    rhombohedral phase;    monoclinic phase;    transmission electron microscopy;    Sb-Bi2Te3;    crystallisation;    SAED;    selected area electron diffraction;   

DOI  :  10.1049/mnl.2015.0457

学科分类：计算机科学（综合）

来源: Wiley

【 摘 要 】

High figures of merit is important and necessary for thermoelectric materials in a particular engineering application of thermoelectric generation. Crystalline is an important factor for the high figures of merit of thermoelectric materials. Single-crystalline structure Sb/Bi2Te3 supperlattice nanowires (SLNWs) were synthesised in large quantity by pulsed electrodeposition technology using porous anodic alumina oxide as a template. The X-ray diffraction result indicates that the as-prepared compound consists of rhombohedral phase Bi2Te3 and monoclinic phase Sb. Transmission electron microscope images demonstrate that the segments of SLNWs are built by Bi2Te3 and Sb alternately and exhibit the distinguished interface between two segments. The average diameter and length of each segment are about 80 and 90 nm, respectively. The composition of neighbouring segments was investigated by selected area electron diffraction (SAED), further verifying that the neighbouring segments of SLNWs are comprised of Bi2Te3 and Sb. Meanwhile, the spot pattern of SAED indicates these segments are crystallised well.

【 授权许可】

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