Characterisation of a bis-ferrocene molecular QCA wire on a non-ideal gold surface

Micro & nano letters

article

Mariagrazia Graziano¹  Ruiyu Wang¹  Massimo Ruo Roch¹  Yuri Ardesi¹  Fabrizio Riente¹  Gianluca Piccinini¹ 

[1] Department of Electronics and Telecommunications

关键词: quantum wires;    quantum dots;    surface roughness;    cellular automata;    molecular electronics;    bis-ferrocene molecular QCA wire;    nonideal gold surface;    field-coupled nanocomputing;    post-CMOS scenario;    field interactions;    molecular quantum-dot cellular automata;    redox centres;    oxidised molecules;    Coulomb interaction;    information propagation;    charge transport;    possible molecular wire;    surface roughness;    information transfer;   

DOI  :  10.1049/mnl.2018.5201

学科分类：计算机科学（综合）

来源: Wiley

【 摘 要 】

Field-coupled nanocomputing represents one of the possible proposals for the post-Complementary Metal Oxide Semiconductor (CMOS) scenario. Contrarily to standard technology, the information is not propagated using electron transport, but via field interactions among single elements. The molecular quantum-dot cellular automata (QCA) is one of the most promising implementations; redox centres of oxidised molecules are used to concentrate charges. Coulomb interaction between redox centres enables the information propagation. The necessity for charge transport is overcome, entailing very low power consumption notwithstanding the nanometric size and the very high expected operating frequency. Nevertheless, as the Coulomb interaction strongly depends on the distance between charges, the position of each molecule plays a relevant role in the interaction. This work investigates the information propagation of a possible molecular wire thiolated on a non-ideal gold surface, where the intermolecular distance may vary due to the surface roughness and possible defects introduced in the formation of the molecular wire. The efficiency of the information transfer is analysed with the aim of providing significant constrains and suggestions for future fabrication steps.

【 授权许可】

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