Influence of the reaction time on the physical–chemical and catalytic properties of vanadium phosphate catalysts prepared by a eutectic mixture

Micro & nano letters

article

Qi Zhang¹  Weiguo Fang²  Qian Li¹ 

[1]Lanzhou Petrochemical College of Vocational Technology

[2]Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences

关键词: catalysis;    nanofabrication;    crystallisation;    desorption;    catalysts;    adsorption;    scanning electron microscopy;    X-ray diffraction;    oxidation;    calcination;    vanadium compounds;    nanostructured materials;    high specific surface area;    eutectic mixture;    reflux duration time;    vanadium phosphate catalysts;    vanadium phosphate materials;    X-ray diffraction;    amorphous phase;    crystallised phase;    reflux duration;    N2 adsorption-desorption measurements;    Brunauer-Emmett-Teller studies;    scanning electron microscopic analysis;    calcination temperature;    growth process;    VPO nanostructures;    benzyl alcohol;    physical-chemical properties;    catalytic properties;    VPO;   

DOI  :  10.1049/mnl.2019.0048

学科分类：计算机科学（综合）

来源: Wiley

【 摘 要 】

Vanadium phosphate (VPO) materials with high specific surface area prepared via a eutectic mixture as solvent and template with different lengths of time, i.e. 24, 72 and 144 h, were investigated in the oxidation of benzyl alcohol. The X-ray diffraction result indicated the initial VPO precursor was an amorphous phase due to the stronger incorporation of eutectic mixture. On subsequent reflux duration of 72 h, the precursor was composed of a crystallised VOHPO 4 ·H 2 O phase. On further reflux duration of 144 h, the incorporated eutectic mixture gradually was leached out and the precursor became more crystalline. Interestingly the N 2 adsorption–desorption measurements Brunauer–Emmett–Teller studies showed that the VPO precursor incorporated eutectic mixture was mesostructured and the specific surface area first increased then decreased with increasing the reflux duration time. The growth process of the VPO nanostructures formed in a eutectic mixture with different lengths of time was investigated by scanning electron microscopic analysis. The influence of calcination temperature and lengths of reflux duration on the activity and selectivity of the VPO catalyst was studied and discussed.

【 授权许可】

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