Nitrogen doped porous carbon derived from nanofibrous polyaniline for CO2 adsorption

Journal of Water and Environmental Nanotechnology

ARTICLE

Khalili, Soodabeh¹  Jahanshahi, Mohsen¹ 

[1] Department of Chemical Engineering, Babol Noshirvani University of Technology

关键词: nano Polyaniline;    Nitrogen doping;    Carbon dioxide adsorption;    Chemical activation;   

DOI  :  10.22090/jwent.2019.04.003

学科分类：数学（综合）

来源: Iranian Environmental Mutagen Society

【 摘 要 】

The objective of this work is to develop a cost-effective carbonaceous CO2 adsorbent. N-doped porous carbon (NDC) with nanopore size was synthesized by KOH activation of nano polyaniline (PANI). PANI synthesized in this work has thin nanofibrillar morphology with different lengths and diameters. The activation process was carried out at 800 °C with KOH/precursor ratio of 2. This adsorbent of carbon exhibits high CO2 adsorption capacity of 1.9 mmol/g at 25 °C under atmospheric pressure. The morphology of PNCs is investigated through different technical methods, such as scanning electron microscopy (SEM), N2 adsorption isotherm at 77 K and Fourier transform infrared spectroscopy (FTIR). The CO2 adsorption experiments were done at three different temperatures (298, 308, and 318 K) and pressure up to 10 bar, and correlated with the Langmuir, Freundlich, and Sips models. The Sips isotherm model presented the best fit to the experimental data. Small values of isosteric heat of adsorption were evaluated based on Clausius–Clapeyron equation showed the physical nature of adsorption mechanism. The high amount of CO2 capture by nanopore size NDC renders it as a promising carrier for practical applications such as gas separation.

【 授权许可】

CC BY