A NEW HOMOGENEOUS ELECTROCATALYST FOR ELECTROCHEMICAL CARBONYLATION OF METHANOL TO DIMETHYL CARBONATE

Química Nova

Xiaoyan Wang¹  Gan Jia¹  Yuting Yu¹  Yanfang Gao¹  Wen Zhang¹  Hong Wang¹  Zhenzhu Cao¹  Jinrong Liu¹ 

关键词: electro-synthesis;    DMC;    homogeneous catalyst;   

DOI  :  10.5935/0100-4042.20150003

来源: SciELO

【 摘 要 】

Electrosynthesis of dimethyl carbonate (DMC) from methanol and carbon monoxide using an Cu(phen)Cl2 catalyst was achieved at room temperature and atmospheric pressure. The catalytic activity of the ligand 1,10-phenanthroline (phen) and the catalytic system were analyzed. The IR characterization results for the complex catalyst showed that copper ions were coordinated by nitrogen atoms of phen. In addition, the effects of the influencing factors, such as reaction time (t), reaction temperature (T) and the surface area of the working electrode (SWE) were studied.

【 授权许可】

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