Hidroformilação do oleato de metila catalisada por complexos de ródio

Química Nova

Ana Nery Furlan Mendes²  Ricardo Gomes Da Rosa¹  José Ribeiro Gregório¹ 

[1] ,Universidade Federal do Espírito Santo Centro Universitário Norte do Espírito Santo Departamento de Ciências NaturaisSão Mateus ES ,Brasil

关键词: methyl oleate;    hydroformylation;    rhodium;   

DOI  :  10.1590/S0100-40422012001000010

来源: SciELO

【 摘 要 】

In this work, we describe the hydroformylation of methyl oleate catalyzed by several rhodium complexes. Parameters including total pressure, phosphorous/rhodium and CO/H2 ratio, temperature and phosphorous ligands were scanned. Total conversion of the starting double bonds was achieved while maintaining excellent selectivity in aldehydes.

【 授权许可】

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