| Química Nova | |
| Avaliação de metodologia eletroquímica no monitoramento da conversão de óleo de girassol em biodiesel | |
| Rogério Adelino De Sousa1  Caue Ribeiro1  | |
| [1] ,Embrapa InstrumentaçãoSão Carlos SP ,Brasil | |
| 关键词: biodiesel; electroanalytical measurement; nanostructured TiO2; | |
| DOI : 10.1590/S0100-40422012000100010 | |
| 来源: SciELO | |
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【 摘 要 】
The development of analytical procedures to evaluate transesterification process is still a challenge in biodiesel production. Then, this paper shows an electroanalytical methodology to transesterification process assessment, proposing the application of nanostructured TiO2 electrodes. The results showed, for sunflower oil - methanol reaction catalyzed by KOH, a reduction peak in - 1050 mV and the gradual appearance of a second peak at - 1160 mV. This peak was observed as originated by the transesterification process and is probably related to intermediates. By measuring the intensity of this peak a kinetic profile was determined, showing that the conversion is almost finished in 2 h.
【 授权许可】
CC BY-NC
All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License
【 预 览 】
| Files | Size | Format | View |
|---|---|---|---|
| RO202103040063769ZK.pdf | 467KB |
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