期刊论文详细信息
Química Nova
Avaliação de metodologia eletroquímica no monitoramento da conversão de óleo de girassol em biodiesel
Rogério Adelino De Sousa1  Caue Ribeiro1 
[1] ,Embrapa InstrumentaçãoSão Carlos SP ,Brasil
关键词: biodiesel;    electroanalytical measurement;    nanostructured TiO2;   
DOI  :  10.1590/S0100-40422012000100010
来源: SciELO
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【 摘 要 】

The development of analytical procedures to evaluate transesterification process is still a challenge in biodiesel production. Then, this paper shows an electroanalytical methodology to transesterification process assessment, proposing the application of nanostructured TiO2 electrodes. The results showed, for sunflower oil - methanol reaction catalyzed by KOH, a reduction peak in - 1050 mV and the gradual appearance of a second peak at - 1160 mV. This peak was observed as originated by the transesterification process and is probably related to intermediates. By measuring the intensity of this peak a kinetic profile was determined, showing that the conversion is almost finished in 2 h.

【 授权许可】

CC BY-NC   
 All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License

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