A síntese do aduto binuclear [Fe(CNBu t)(CO)4(HgSO4 )]

Química Nova

Milton K. Morigaki²  Elias M. Da Silva²  Eliana A. Dos Santos²  Carlos Larica¹  Armando Biondo¹  Gilson H. M. Dias¹ 

[1] ,Universidade Federal do Espírito Santo Centro de Ciências Exatas Departamento de QuímicaVitória ES

关键词: isocyanide;    carbonyl;    Mössbauer;   

DOI  :  10.1590/S0100-40422001000300002

来源: SciELO

【 摘 要 】

The binuclear [Fe(CNBu t)(CO)4(HgSO4 )] adduct was obtained in the reaction of HgSO4 with [Fe(CNBu t)(CO)4] in methanol. This adduct, without a similar in the homoleptic pentacarbonyliron, was characterized by analytical and spectroscopic data. Further Mössbauer and molar conductivity studies have confirmed it's adduct nature.

【 授权许可】

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