Towards an atomic level understanding of niobia based catalysts and catalysis by combining the science of catalysis with surface science

Anais da Academia Brasileira de Ciências

Martin Schmal²  Hans-joachim Freund¹ 

[1] ,UFRJ Coppe Centro de TecnologiaRio de Janeiro RJ ,Brasil

关键词: catalysis;    model catalysts;    cobalt;    palladium;    characterization;    niobia;    catálise;    catalisadores modelo;    cobalto;    paládio;    caracterização;    nióbia;   

DOI  :  10.1590/S0001-37652009000200016

来源: SciELO

【 摘 要 】

The science of catalysis and surface science have developed, independently, key information for understanding catalytic processes. One might argue: is there anything fundamental to be discovered through the interplay between catalysis and surface science? Real catalysts of monometallic and bimetallic Co/Nb2O5 and Pd-Co/Nb2O5 catalysts showed interesting selectivity results on the Fischer-Tropsch synthesis (Noronha et al. 1996, Rosenir et al. 1993). The presence of a noble metal increased the C+5 selectivity and decreased the methane formation depending of the reduction temperature. Model catalyst of Co-Pd supported on niobia and alumina were prepared and characterized at the atomic level, thus forming the basis for a comparison with "real" support materials. Growth, morphology and structure of both pure metal and alloy particles were studied. It is possible to support the strong metal support interaction suggested by studies on real catalysts via the investigation of model systems for niobia in comparison to alumina support in which this effect does not occur. Formation of Co2+ penetration into the niobia lattice was suggested on the basis of powder studies and can be fully supported on the basis of model studies. It is shown for both real catalysts and model systems that oxidation state of Co plays a key role in controlling the reactivity in Fischer-Tropsch reactions systems and that the addition of Pd is a determining factor for the stability of the catalyst. It is demonstrated that the interaction with unsaturated hydrocarbons depends strongly on the state of oxidation.

【 授权许可】

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