Effect of reinforcement nanoparticles addition on mechanical properties of SBS/curauá fiber composites

Materials Research

Patricia M Borba²  Adriana Tedesco¹  Denise M Lenz¹ 

[1] ,Centro Tecnológico de Polímeros Serviço Nacional de Aprendizagem Industrial São Leopoldo RS ,Brazil

关键词: SBS copolymer;    montmorillonite;    vegetable fiber;    mechanical properties;   

DOI  :  10.1590/S1516-14392013005000203

来源: SciELO

【 摘 要 】

Composites of styrene-butadiene-styrene triblock copolymer (SBS) matrix with curauá fiber and/or a nanoparticulate mineral (montmorillonite clay - MMT) used as reinforcing agents were prepared by melt-mixing. The influence of clay addition on properties like tensile and tear strength, rebound resilience, flex fatigue life, abrasion loss, hardness and water absorption of composites with 5, 10 and 20 wt% of curauá fiber was evaluated in presence of maleic anhydride grafted styrene-(ethylene-co-butylene)-styrene triblock copolymer (MA-g-SEBS) coupling agent. Furthermore, the effect of mineral plasticizer loading on tensile strength of selected composites was investigated. The hybrid SBS composite that showed the best overall mechanical performance was composed by 2 wt% of MMT and 5 wt% of curauá fiber. Increasing fiber content up to 20 wt% resulted in a general decrease in all mechanical properties as well as incorporation of 5 wt% MMT caused a decrease in the tensile strength in all fiber contents. The hybrid composites showed clay agglomerates (tactoids) poorly dispersed that could explain the poor mechanical performance of composites at higher concentrations of curauá fiber and MMT nanoparticles. The addition of plasticizer further decreased the tensile strength while the addition of MMT nanoparticles decreased water absorption for all SBS composites.

【 授权许可】

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