Sintering behavior of LZSA glass-ceramics

Materials Research

Oscar Rubem Klegues Montedo¹  Fernando Joaquim Floriano¹  Jaime De Oliveira Filho¹  Elídio Angoletto¹  Adriano Michael Bernardin¹ 

[1] ,Unidade Acadêmica de Ciências, Engenharias e Tecnologia

关键词: ceramics;    glass;    glass-ceramics;    LZSA system;    sintering;    crystallization;   

DOI  :  10.1590/S1516-14392009000200014

来源: SciELO

【 摘 要 】

The LZSA glass-ceramic system (Li2O-ZrO2-SiO2-Al2O 3) shows interesting properties, such as good chemical resistance, low thermal expansion, high abrasion resistance, and a low dielectric constant. However, in order to obtain a high performance material for specific applications, the sintering behavior must be better understood so that the porosity may be reduced and other properties improved. In this context, a sintering investigation for a specific LZSA glass-ceramic system composition was carried out. A 18.8Li2O-8.3ZrO2-64.2SiO2-8.7Al 2O3 glass was prepared by melting the solids, quenching the melt in water, and grinding the resulting solid in order to obtain a powder (3.68 μm average particle diameter). Subsequently, the glass powder was characterized (chemical analysis and determination of thermal properties) and the sintering behavior was investigated using optical non-contact dilatometry measurements. The results showed that the crystallization process strongly reduced the sintering in the temperature interval from 785 to 940 °C, and a maximum thermal shrinkage of 15.4% was obtained with operating conditions of 1020 °C and 180 minutes.

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