Identification of Extra-Framework Species on Fe/ZSM-5 and Cu/ZSM-5 Catalysts Typical Microporous Molecular Sieves with Zeolitic Structure

Materials Research

E.a. Urquieta-gonzález¹  L. Martins¹  R.p.s. Peguin¹  M.s. Batista¹ 

[1] ,Universidade Federal de São Carlos Departamento de Engenharia Química São Carlos SP ,Brazil

关键词: Cu/ZSM-5;    Fe/ZSM-5;    XRD;    DRS-UV;    H2-TPR;    EPR;    Mössbauer Spectroscopy;   

DOI  :  10.1590/S1516-14392002000300017

来源: SciELO

【 摘 要 】

Cu and Fe species formed during the preparation of Cu/ and Fe/ZSM-5 catalysts by ion exchange were studied. XRD, SEM, H2-TPR, DRS-UV-VIS, EPR, Mössbauer Spectroscopy (MÖSS) and chemical analysis (AAS) were used to sample characterization. Cu/ZSM-5 catalysts, irrespective of their Si/Al ratio and Cu content, showed a reduction peak at around 210°C, which was attributed to the reduction of Cu+2 to Cu+1. The reduction peak of Cu+1 to Cu0 shifted to higher temperatures with the increase of Si/Al ratio or with the diminution of Cu/Al ratio, evidencing that isolated Cu cations present a higher interaction with the zeolite structure. The MÖSS data showed the presence of Fe+3 species in charge-compensation sites and a higher content of hematite (Fe2O3) in the catalysts prepared in aqueous medium. The EPR analysis also evidenced the Cu+2 and Fe+3 presence in Cu and Fe/ZSM-5 catalysts, respectively.

【 授权许可】

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