Synthesis and characterization of new 3-substituted thiophene copolymers

Journal of the Brazilian Chemical Society

Marcos R. A Alves¹  Hállen D. R Calado¹  Claudio L Donnici¹  Tulio Matencio¹ 

[1] ,Universidade Federal de Minas Gerais ICEx Departamento de QuimicaBelo Horizonte MG ,Brazil

关键词: conjugated polymer;    copolymer;    3-substituted thiophene;    photoluminescence;   

DOI  :  10.1590/S0103-50532011000200009

来源: SciELO

【 摘 要 】

This work reports the synthesis of three polymers and two new copolymers based on 3-substituted polythiophene derivatives, all of them demonstrated photoluminescent properties. All polymers synthesized, i.e., poly(3-methoxythiophene) (PMOT), poly(3-thiopheneethanol) (PTE), poly(3-thiophenemethanol) (PTM), poly(3-methoxythiophene-co-3-thiopheneethanol) (PMOT-co-TE) and poly(3-methoxythiophene-co-3-thiophenemethanol) (PMOT-co-TM), were characterized by FT IR, UV-Vis, photoluminescence (PL), thermal analysis (TG and DSC) and X-ray diffraction (XRD). All materials emitted light in the orange region of the visible spectrum. Spectrometric analysis in the infrared region demonstrated the successful synthesis of polymers and copolymers by the presence of characteristic bands. Thermal analysis showed that the obtained materials had good thermal stability.

【 授权许可】

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