Spin-exchange effects in elastic electron scattering from linear triatomic radicals

Journal of the Brazilian Chemical Society

M. M. Fujimoto²  S. E. Michelin¹  F. Arretche¹  K.t. Mazon¹  M.-t. Lee¹  I. Iga¹ 

[1] ,Universidade Federal do Paraná Departamento de Física Curitiba PR ,Brazil

关键词: spin-flip;    NCN;    CNN;    elastic collision;    ISVM;   

DOI  :  10.1590/S0103-50532010000200006

来源: SciELO

【 摘 要 】

In this work, we present a theoretical investigation on spin-exchange effects in elastic electron collisions by two linear triatomic free radicals namely, NCN and CNN. Spin-polarization differential and integral cross sections calculated in the (1-10) eV energy range are reported. For both targets, our study has shown that the exchange between the scattering and the unpaired target electrons is strongly influenced by the occurrence of shape resonances. As a consequence, significant spin-polarization fractions are only observed in the resonance region.

【 授权许可】

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