New flavonoids and other constituents from Ouratea hexasperma (Ochnaceae)

Journal of the Brazilian Chemical Society

Mário G. De Carvalho²  Luciano R. Suzart²  Lorena C. Cavatti²  Maria Auxiliadora C. Kaplan¹ 

[1] ,Universidade Federal Rural do Rio de Janeiro Departamento de Química Rio de Janeiro RJ ,Brazil

关键词: Ochnaceae;    Ouratea hexasperma;    glucopyranosyl-prenylflavonoids;    prenylflavanonol glucoside;    prenylflavone glucoside;    2;    4-dihydroxyphenylacetic acid;   

DOI  :  10.1590/S0103-50532008000700029

来源: SciELO

【 摘 要 】

Chromatographical fractionation of the methanol extract from the branches of Ouratea hexasperma (Ochnaceae) afforded two new flavonoids, 7-O-β-D-glucopyranosyl-6-(3-methylbut-2-enyl)-5,4'-dihydroxyflavanonol (6-β,β-dimethylallylaromadendrin-7-O-β-D-glucoside) and 7-O-β-D-glucopyranosyl-6-(3-methylbut-2-enyl)-3,5,4'-trihydroxyflavone (6-β,β-dimethylallylkaempferol-7-O-β-D-glucoside) besides a mixture of sitosterol and stigmasterol,lupeol, sitosterol-3-O-β-D-glycopyranoside and 2,4-dihydroxyphenylacetic acid. The structures were established by analysis of IR, ESI-MS, and NMR spectra of the natural substances, and those of the dimethyl ether and peracetyl-derivatives of the new flavone, as well as comparison with literature values.

【 授权许可】

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