A Novel and highly selective conversion of alcohols, thiols, and silyl ethers to azides using the 2,4,6-trichloro[1,3,5]triazine/n-Bu4NN3 system

Journal of the Brazilian Chemical Society

Batool Akhlaghinia¹  Sima Samiei¹ 

[1] ,Damghan University of Basic Sciences School of Chemistry Damghan,Iran

关键词: 2;    4;    6-trichloro[1;    3;    5] triazine (TT);    alcohol;    thiol;    trimethylsilyl ether;    alkyl azide;   

DOI  :  10.1590/S0103-50532007000700003

来源: SciELO

【 摘 要 】

Alkyl azides are prepared in good to excellent yields by treatment of alcohols, thiols and trimethylsilyl ethers with 2,4,6-trichloro[1,3,5]triazine/n-Bu4NN 3 in acetonitrile. This method is highly selective for conversion of primary alcohols to alkyl azides in the presence of secondary and tertiary alcohols, thiols and trimethysilyl ethers.

【 授权许可】

CC BY   
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