3-phenyl-4-acyl-5-isoxazolones as reagents for liquid-liquid extraction of tetravalent zirconium and hafnium from acidic chloride solutions

Journal of the Brazilian Chemical Society

B. Ramachandra Reddy²  J. Rajesh Kumar¹  A. Varada Reddy¹ 

[1] ,Indian Institute of Chemical Technology Inorganic Chemistry Division ,India

关键词: 3-phenyl-4-acyl-5-isoxazolones;    extraction;    zirconium(IV);    hafnium(IV);    acidic chloride solutions;   

DOI  :  10.1590/S0103-50532006000400021

来源: SciELO

【 摘 要 】

Liquid liquid extraction of tetravalent zirconium and hafnium from acidic chloride solutions has been investigated using 3-phenyl-4-acyl-5-isoxazolones in xylene such as 3-phenyl-4-benzoyl-5-isoxazolones (HPBI), 3-phenyl-4-(4-fluorobenzoyl)-5-isoxazolone (HFBPI) and 3-phenyl-4-(4-toluoyl)-5-isoxazolone (HTPI). The extraction of zirconium(IV) / hafnium(IV) shows a ion exchange mechanism: MO2+ (aq) + 2 HA (org) « MOA2 (org) + 2 H+(aq), where M = Zr(IV) / Hf(IV) and HA = HPBI or HFBPI or HTPI. The variation of the D ([MOA2] (org) / [MO2+](aq); ratio of the possible extraction equilibrium species) values with an increase of the acid / extractant concentration showed a linear plot with a slope of 2. The effect of the nature of the diluents like carbon tetrachloride, cyclohexane, n-hexane, benzene, nitrobenzene, xylene, toluene and chloroform on the extraction of zirconium(IV) / hafnium(IV) has been studied. The extraction behavior of zirconium(IV) / hafnium(IV) was also compared with that of other metal ions like titanium(IV), aluminium(III) and iron(III), which can be generally associated with the metal ions studied.

【 授权许可】

CC BY   
 All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License