Evaluation of the anticorrosive properties of environmental friendly inorganic corrosion inhibitors pigments

Journal of the Brazilian Chemical Society

Adriana O. S. Leite²  Walney S. Araújo²  Isabel C.p. Margarit¹  Adriana N. Correia²  Pedro De Lima-neto² 

[1] ,Universidade Federal do Ceará Departamento de Química Analítica e Físico-Química Fortaleza CE ,Brazil

关键词: steel;    corrosion;    anticorrosive pigments;    mass loss;    electrochemical tests;    surface analysis;   

DOI  :  10.1590/S0103-50532005000500013

来源: SciELO

【 摘 要 】

Anticorrosive properties of the following environmental friendly inorganic pigments were evaluated: zinc phosphate (ZP), zinc molybdate (ZM), zinc calcium molybdate (ZCM), zinc phosphomolybdate (ZPM) and zinc calcium phosphomolybdate (ZCPM). AISI 1010 steel samples were immersed in 10-2 mol dm-3 NaCl aqueous solution saturated with one of the pigments, followed by mass loss measurements, by monitoring the open circuit potential with immersion time and by potentiodynamic linear polarization at 1 mV s-1. The corrosion products on the steel surface were characterized by Scanning Electron Microscopy, Energy Dispersive X-ray and X-rays Diffraction analyses. All the pigments inhibited the corrosion of steel. The films formed on the steel surface protect the substrate against corrosion. The results suggest a synergic effect of phosphate and molybdate compounds in the phosphomolybdate-based pigments, improving the corrosion resistance of steel. The ZMP and ZCPM decreased the corrosion rate by a factor of 2.15 and 3.50, respectively.

【 授权许可】

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