A short and efficient enantioselective synthesis of (+) and (-)-(Z)-7,15-hexadecadien-4-olide: the sex pheromone of the yellowish elongate chafer, Heptophylla picea

Journal of the Brazilian Chemical Society

Giuliano C. Clososki¹  Luis C. Ricci¹  Carlos E. Costa¹  João V. Comasseto¹ 

[1] ,Universidade de São Paulo Instituto de Química São Paulo SP ,Brazil

关键词: pheromone;    Heptophylla picea;    lipase;   

DOI  :  10.1590/S0103-50532004000600004

来源: SciELO

【 摘 要 】

The (R) and the (S) enantiomers of the Z-7,15-hexadecadien-4-olide (4), the sex pheromone of Heptophylla picea, were synthesized. A known lipase-catalysed enantiolactonization in the key step afforded a common precursor for both enantiomers of the pheromone in 92% e.e.

【 授权许可】

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