Clustering of comb and propolis waxes based on the distribution of aliphatic constituents

Journal of the Brazilian Chemical Society

Angela R. Custodio²  Márcia M. C. Ferreira¹  Giuseppina Negri¹  Antonio Salatino¹ 

[1] ,Universidade São FranciscoBragança Paulista SP ,Brazil

关键词: propolis wax;    comb wax;    hydrocarbons;    wax esters;    Hierarchic Cluster Analysis;   

DOI  :  10.1590/S0103-50532003000300003

来源: SciELO

【 摘 要 】

Chemical composition data for 41 samples of propolis waxes and 9 samples of comb waxes of Apis mellifera collected mainly in Brazil were treated using Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA). For chemometrical analysis, the distribution of hydrocarbons and residues of alcohols and carboxylic acids of monoesters were considered. The clustering obtained revealed chemical affinities and differences not previously grasped by simple eye-inspection of the data. No consistent differences were detected between comb and propolis waxes. These and previous results suggest that hydrocarbons, carboxylic acids, aliphatic alcohols and esters from both comb and propolis waxes are bee-produced compounds and, hence, the differences detected between one and another region are dependent on genetic factors related to the insects rather than the local flora. The samples analyzed were split into two main clusters, one of them comprising exclusively material collected in the State of São Paulo. The results are discussed with respect to the africanization of honeybees that first took place in that State and therefrom irradiated to other parts of Brazil.

【 授权许可】

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