Avaliação do potencial anticorrosivo de tiossemicarbazonas solubilizadas em microemulsão

Química Nova

Elaine Cristina M. De Moura²  Adna Dornelles N. Souza²  Cátia Guaraciara F. T. Rossi²  Djalma R. Da Silva²  Maria Aparecida M. Maciel²  Aurea Echevarria¹  Myrtes S. S. Bellieny¹ 

[1] ,Universidade Federal do Rio Grande do Norte Instituto de Química Natal RN ,Brasil

关键词: thiosemicarbazones;    microemulsion;    corrosion inhibitors;   

DOI  :  10.1590/S0100-40422013000100011

来源: SciELO

【 摘 要 】

In this paper, thiosemicarbazones 4-N-cinnamoyl-thiosemicarbazone (CTSC), 4-N-(2'-methoxycinnamoyl)-thiosemicarbazone (MCTSC), and 4-N-(4'-hydroxy-3'-methoxybenzoyl)- thiosemicarbazone (HMBTSC) were solubilized in an oil-in-water (O/W) microemulsion system (ME_OCS), forming systems CTSC_ME_OCS, MCTSC_ME_OCS and HMBTSC_ME_OCS. The effectiveness of these systems in the process of inhibiting AISI 1020 carbon steel corrosion was evaluated in a saline solution (NaCl 0.5%), using a galvanostatic method. The tested thiosemicarbazones showed higher inhibitory effects (85.7% for CTSC_ME_OCS, 84.0% for MCTSC_ME_OCS, and 83.3% for HMBTSC_ME_OCS). The surfactant OCS (dissolved in H2O) and the ME_OCS system showed lower efficacies, with 71.0% for OCS and 74.0% for ME_OCS system.

【 授权许可】

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