期刊论文详细信息
Química Nova
Optimization of the use of carbon paste electrodes (CPE) for electrochemical study of the chalcopyrite
Daniela G. Horta1  Denise Bevilaqua1  Heloísa A. Acciari1  Oswaldo Garcia Júnior1  Assis V. Benedetti1 
[1] ,Universidade Estadual Paulista Instituto de Química Araraquara SP ,Brasil
关键词: carbon paste electrodes (CPE);    chalcopyrite;    leaching;   
DOI  :  10.1590/S0100-40422009000700010
来源: SciELO
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【 摘 要 】

The use of carbon paste electrodes (CPE) of mineral sulfides can be useful for electrochemical studies to overcome problems by using massive ones. Using CPE-chalcopyrite some variables were electrochemically evaluated. These variables were: (i) the atmosphere of preparation (air or argon) of CPE and elapsed time till its use; (ii) scan rate for voltammetric measurements and (iii) chalcopyrite concentration in the CPE. Based on cyclic voltammetry, open-circuit potential and electrochemical impedance results the recommendations are: oxygen-free atmosphere to prepare and kept the CPE until around two ours, scan rates from 10 to 40 mV s-1, and chalcopyrite concentrations > 20%.

【 授权许可】

CC BY-NC   
 All the contents of this journal, except where otherwise noted, is licensed under a Creative Commons Attribution License

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